A substantial amount of what Shannon Lush says about the chemistry of cleaning is wrong. This shouldn’t surprise us, as she is not a chemist.
Paramount among these is the oft-given advice of mixing bicarb with vinegar. I have heard her say on air that this “makes hydrogen peroxide” and that’s what does the cleaning.
This is quite incorrect, and I and several of my colleagues have sent her emails in this regard down through the years. She apparently now realises this, as on Tony Delroy’s show on nightlife this evening she said that it “forces oxygen into things”
I was unable to get an explanation of this, however. For her benefit, when you mix bicarb soda and vinegar together, the reaction products are sodium acetate, water and carbon dioxide, not oxygen, and none of these compounds have any cleaning properties whatever.
The balanced equation is:
NaHCO3 + CH3COOH = NaCH3COO + H2O + CO2
But let it never said I wasn’t open-minded. I now invite Shannon Lush to answer this question, and I’ll print her answer in full on this site.
Other things that she said that were wrong (off the top of my head) were
1. You cannot remove silicone (from Mr Sheen) from a plasma TV. I’m not sure why you’d want to remove Mr Sheen, as it is a terrific general purpose cleaner, but it can be removed with Shellite (from a hardware store) – that’s what painters use to pretreat automotive surfaces that have often been polished with silicone polishes.
2. You cannot use an acidic cleaner to clean marble. In fact marble is incredibly chemically resilient, which is why we still have marble structures going back to Roman times, and you can use hydrochloric acid on it if you want. But if the problem was mould and mildew, you’d use caustic soda on it.
3. You can mostly replace your laundry powder with bicarb soda. This advice displays an utter ignorance of both the chemistry of bicarb soda and washing powders. Washing powders are highly sophisticated formulas that contain up to 9 or 10 different components (surfactants, enzymes, oxidizers, builders, alkaline salts, fluorescing agents, antiredeposition agents, free-flow agents, fragrance, softeners), and you simply cannot replace these with any one chemical – particularly bicarb soda, which has almost no cleaning properties whatever.